<?xml version="1.0"?>
<ctml>
  <validate species="yes" reactions="yes"/>

  <!-- phase gas     -->
  <phase id="gas" dim="3">
    <elementArray datasrc="elements.xml">O H C N Ar</elementArray>
    <speciesArray datasrc="gri30.xml#species_data">
      H2      H       O       O2      OH
      H2O     HO2     H2O2
      C       CH      CH2     CH2(S)  CH3     CH4     CO      CO2
      HCO     CH2O    CH2OH   CH3O    CH3OH   C2H     C2H2    C2H3
      C2H4    C2H5    C2H6    HCCO    CH2CO   HCCOH AR N2
      <skip element="undeclared"/>
    </speciesArray>
    <reactionArray datasrc="gri30.xml#reaction_data">
      <skip species="undeclared"/>
    </reactionArray>
    <state>
      <temperature units="K">300.0</temperature>
      <pressure units="Pa">101325.0</pressure>
      <moleFractions>CH4:0.095, O2:0.21, AR:0.79</moleFractions>
    </state>
    <thermo model="IdealGas"/>
    <kinetics model="GasKinetics"/>
    <transport model="Mix"/>
  </phase>

  <!-- phase Pt_surf     -->
  <phase id="Pt_surf" dim="2">
    <elementArray datasrc="elements.xml">Pt  H  O  C </elementArray>
    <speciesArray datasrc="ptcombust.xml#species_data">
      PT(S) H(S) H2O(S)  OH(S)  CO(S)
      CO2(S)  CH3(S) CH2(S)s  CH(S)  C(S)  O(S) </speciesArray>
    <reactionArray datasrc="#reaction_data"/>
    <state>
      <temperature units="K">900.0</temperature>
      <coverages>O(S):0.0, PT(S):0.5, H(S):0.5</coverages>
    </state>
    <thermo model="Surface">
      <site_density units="mol/cm2">2.7063e-09</site_density>
    </thermo>
    <kinetics model="Interface"/>
    <transport model="None"/>
    <phaseArray>gas</phaseArray>
  </phase>

  <!-- species definitions     -->
  <speciesData id="species_data"/>
  <reactionData id="reaction_data" motz_wise="true">

    <!-- reaction 0001    -->
    <reaction id="0001" reversible="no" type="surface">
      <equation>H2 + 2 PT(S) =] 2 H(S)</equation>
      <order species="H2">1.0</order>
      <order species="PT(S)">1.0</order>
      <rateCoeff>
        <Arrhenius>
          <A>4.457900E+07</A>
          <b>0.5</b>
          <E units="J/mol">0.000000</E>
        </Arrhenius>
      </rateCoeff>
      <reactants>H2:1.0 PT(S):2.0</reactants>
      <products>H(S):2.0</products>
    </reaction>

    <!-- reaction 0002    -->
    <reaction id="0002" reversible="no" type="surface">
      <equation>2 H(S) =] H2 + 2 PT(S)</equation>
      <rateCoeff>
        <Arrhenius>
          <A>3.700000E+20</A>
          <b>0</b>
          <E units="J/mol">67400.000000</E>
          <coverage species="H(S)">
            <a>0.000000</a>
            <m>0.0</m>
            <e units="J/mol">-6000.000000</e>
          </coverage>
        </Arrhenius>
      </rateCoeff>
      <reactants>H(S):2.0</reactants>
      <products>H2:1.0 PT(S):2.0</products>
    </reaction>

    <!-- reaction 0003    -->
    <reaction id="0003" reversible="no" type="surface">
      <equation>H + PT(S) =] H(S)</equation>
      <rateCoeff>
        <Arrhenius type="stick" species="H">
          <A>1.000000E+00</A>
          <b>0</b>
          <E units="J/mol">0.000000</E>
        </Arrhenius>
      </rateCoeff>
      <reactants>H:1.0 PT(S):1</reactants>
      <products>H(S):1.0</products>
    </reaction>

    <!-- reaction 0004    -->
    <reaction id="0004" reversible="no" duplicate="yes" type="surface">
      <equation>O2 + 2 PT(S) =] 2 O(S)</equation>
      <rateCoeff>
        <Arrhenius>
          <A>1.800000E+17</A>
          <b>-0.5</b>
          <E units="J/mol">0.000000</E>
        </Arrhenius>
      </rateCoeff>
      <reactants>O2:1.0 PT(S):2.0</reactants>
      <products>O(S):2.0</products>
    </reaction>

    <!-- reaction 0005    -->
    <reaction id="0005" reversible="no" duplicate="yes" type="surface">
      <equation>O2 + 2 PT(S) =] 2 O(S)</equation>
      <rateCoeff>
        <Arrhenius type="stick" species="O2" motz_wise="false">
          <A>2.300000E-02</A>
          <b>0</b>
          <E units="J/mol">0.000000</E>
        </Arrhenius>
      </rateCoeff>
      <reactants>O2:1.0 PT(S):2.0</reactants>
      <products>O(S):2.0</products>
    </reaction>

    <!-- reaction 0006    -->
    <reaction id="0006" reversible="no" type="surface">
      <equation>2 O(S) =] O2 + 2 PT(S)</equation>
      <rateCoeff>
        <Arrhenius>
          <A>3.700000E+20</A>
          <b>0</b>
          <E units="J/mol">213200.000000</E>
          <coverage species="O(S)">
            <a>0.000000</a>
            <m>0.0</m>
            <e units="J/mol">-60000.000000</e>
          </coverage>
        </Arrhenius>
      </rateCoeff>
      <reactants>O(S):2.0</reactants>
      <products>O2:1.0 PT(S):2.0</products>
    </reaction>

    <!-- reaction 0007    -->
    <reaction id="0007" reversible="no" type="surface">
      <equation>O + PT(S) =] O(S)</equation>
      <rateCoeff>
        <Arrhenius type="stick" species="O">
          <A>1.000000E+00</A>
          <b>0</b>
          <E units="J/mol">0.000000</E>
        </Arrhenius>
      </rateCoeff>
      <reactants>O:1.0 PT(S):1</reactants>
      <products>O(S):1.0</products>
    </reaction>

    <!-- reaction 0008    -->
    <reaction id="0008" reversible="no" type="surface">
      <equation>H2O + PT(S) =] H2O(S)</equation>
      <rateCoeff>
        <Arrhenius type="stick" species="H2O">
          <A>7.500000E-01</A>
          <b>0</b>
          <E units="J/mol">0.000000</E>
        </Arrhenius>
      </rateCoeff>
      <reactants>H2O:1.0 PT(S):1</reactants>
      <products>H2O(S):1.0</products>
    </reaction>

    <!-- reaction 0009    -->
    <reaction id="0009" reversible="no" type="surface">
      <equation>H2O(S) =] H2O + PT(S)</equation>
      <rateCoeff>
        <Arrhenius>
          <A>1.000000E+13</A>
          <b>0</b>
          <E units="J/mol">40300.000000</E>
        </Arrhenius>
      </rateCoeff>
      <reactants>H2O(S):1.0</reactants>
      <products>H2O:1.0 PT(S):1</products>
    </reaction>

    <!-- reaction 0010    -->
    <reaction id="0010" reversible="no" type="surface">
      <equation>OH + PT(S) =] OH(S)</equation>
      <rateCoeff>
        <Arrhenius type="stick" species="OH" motz_wise="true">
          <A>1.000000E+00</A>
          <b>0</b>
          <E units="J/mol">0.000000</E>
        </Arrhenius>
      </rateCoeff>
      <reactants>OH:1.0 PT(S):1</reactants>
      <products>OH(S):1.0</products>
    </reaction>

    <!-- reaction 0011    -->
    <reaction id="0011" reversible="no" type="surface">
      <equation>OH(S) =] OH + PT(S)</equation>
      <rateCoeff>
        <Arrhenius>
          <A>1.000000E+13</A>
          <b>0</b>
          <E units="J/mol">192800.000000</E>
        </Arrhenius>
      </rateCoeff>
      <reactants>OH(S):1.0</reactants>
      <products>OH:1.0 PT(S):1</products>
    </reaction>

    <!-- reaction 0012    -->
    <reaction id="0012" reversible="yes" type="surface">
      <equation>H(S) + O(S) [=] OH(S) + PT(S)</equation>
      <rateCoeff>
        <Arrhenius>
          <A>3.700000E+20</A>
          <b>0</b>
          <E units="J/mol">11500.000000</E>
        </Arrhenius>
      </rateCoeff>
      <reactants>H(S):1.0 O(S):1</reactants>
      <products>OH(S):1.0 PT(S):1</products>
    </reaction>

    <!-- reaction 0013    -->
    <reaction id="0013" reversible="yes" type="surface">
      <equation>H(S) + OH(S) [=] H2O(S) + PT(S)</equation>
      <rateCoeff>
        <Arrhenius>
          <A>3.700000E+20</A>
          <b>0</b>
          <E units="J/mol">17400.000000</E>
        </Arrhenius>
      </rateCoeff>
      <reactants>H(S):1.0 OH(S):1</reactants>
      <products>H2O(S):1.0 PT(S):1</products>
    </reaction>

    <!-- reaction 0014    -->
    <reaction id="0014" reversible="yes" type="surface">
      <equation>OH(S) + OH(S) [=] H2O(S) + O(S)</equation>
      <rateCoeff>
        <Arrhenius>
          <A>3.700000E+20</A>
          <b>0</b>
          <E units="J/mol">48200.000000</E>
        </Arrhenius>
      </rateCoeff>
      <reactants>OH(S):2.0</reactants>
      <products>H2O(S):1.0 O(S):1</products>
    </reaction>

    <!-- reaction 0015    -->
    <reaction id="0015" reversible="no" type="surface">
      <equation>CO + PT(S) =] CO(S)</equation>
      <order species="CO">1.0</order>
      <order species="PT(S)">2.0</order>
      <rateCoeff>
        <Arrhenius>
          <A>1.618000E+16</A>
          <b>0.5</b>
          <E units="J/mol">0.000000</E>
        </Arrhenius>
      </rateCoeff>
      <reactants>CO:1.0 PT(S):1</reactants>
      <products>CO(S):1.0</products>
    </reaction>

    <!-- reaction 0016    -->
    <reaction id="0016" reversible="no" type="surface">
      <equation>CO(S) =] CO + PT(S)</equation>
      <rateCoeff>
        <Arrhenius>
          <A>1.000000E+13</A>
          <b>0</b>
          <E units="J/mol">125500.000000</E>
        </Arrhenius>
      </rateCoeff>
      <reactants>CO(S):1.0</reactants>
      <products>CO:1.0 PT(S):1</products>
    </reaction>

    <!-- reaction 0017    -->
    <reaction id="0017" reversible="no" type="surface">
      <equation>CO2(S) =] CO2 + PT(S)</equation>
      <rateCoeff>
        <Arrhenius>
          <A>1.000000E+13</A>
          <b>0</b>
          <E units="J/mol">20500.000000</E>
        </Arrhenius>
      </rateCoeff>
      <reactants>CO2(S):1.0</reactants>
      <products>CO2:1.0 PT(S):1</products>
    </reaction>

    <!-- reaction 0018    -->
    <reaction id="0018" reversible="no" type="surface">
      <equation>CO(S) + O(S) =] CO2(S) + PT(S)</equation>
      <rateCoeff>
        <Arrhenius>
          <A>3.700000E+20</A>
          <b>0</b>
          <E units="J/mol">105000.000000</E>
        </Arrhenius>
      </rateCoeff>
      <reactants>CO(S):1.0 O(S):1</reactants>
      <products>CO2(S):1.0 PT(S):1</products>
    </reaction>

    <!-- reaction 0019    -->
    <reaction id="0019" reversible="no" type="surface">
      <equation>CH4 + 2 PT(S) =] CH3(S) + H(S)</equation>
      <order species="CH4">1.0</order>
      <order species="PT(S)">2.3</order>
      <rateCoeff>
        <Arrhenius>
          <A>2.322201E+16</A>
          <b>0.5</b>
          <E units="J/mol">0.000000</E>
        </Arrhenius>
      </rateCoeff>
      <reactants>CH4:1.0 PT(S):2.0</reactants>
      <products>CH3(S):1.0 H(S):1</products>
    </reaction>

    <!-- reaction 0020    -->
    <reaction id="0020" reversible="no" type="surface">
      <equation>CH3(S) + PT(S) =] CH2(S)s + H(S)</equation>
      <rateCoeff>
        <Arrhenius>
          <A>3.700000E+20</A>
          <b>0</b>
          <E units="J/mol">20000.000000</E>
        </Arrhenius>
      </rateCoeff>
      <reactants>CH3(S):1.0 PT(S):1</reactants>
      <products>CH2(S)s:1.0 H(S):1</products>
    </reaction>

    <!-- reaction 0021    -->
    <reaction id="0021" reversible="no" type="surface">
      <equation>CH2(S)s + PT(S) =] CH(S) + H(S)</equation>
      <rateCoeff>
        <Arrhenius>
          <A>3.700000E+20</A>
          <b>0</b>
          <E units="J/mol">20000.000000</E>
        </Arrhenius>
      </rateCoeff>
      <reactants>CH2(S)s:1.0 PT(S):1</reactants>
      <products>CH(S):1.0 H(S):1</products>
    </reaction>

    <!-- reaction 0022    -->
    <reaction id="0022" reversible="no" type="surface">
      <equation>CH(S) + PT(S) =] C(S) + H(S)</equation>
      <rateCoeff>
        <Arrhenius>
          <A>3.700000E+20</A>
          <b>0</b>
          <E units="J/mol">20000.000000</E>
        </Arrhenius>
      </rateCoeff>
      <reactants>CH(S):1.0 PT(S):1</reactants>
      <products>C(S):1.0 H(S):1</products>
    </reaction>

    <!-- reaction 0023    -->
    <reaction id="0023" reversible="no" type="surface">
      <equation>C(S) + O(S) =] CO(S) + PT(S)</equation>
      <rateCoeff>
        <Arrhenius>
          <A>3.700000E+20</A>
          <b>0</b>
          <E units="J/mol">62800.000000</E>
        </Arrhenius>
      </rateCoeff>
      <reactants>C(S):1.0 O(S):1</reactants>
      <products>CO(S):1.0 PT(S):1</products>
    </reaction>

    <!-- reaction 0024    -->
    <reaction id="0024" reversible="no" type="surface">
      <equation>CO(S) + PT(S) =] C(S) + O(S)</equation>
      <rateCoeff>
        <Arrhenius>
          <A>1.000000E+17</A>
          <b>0</b>
          <E units="J/mol">184000.000000</E>
        </Arrhenius>
      </rateCoeff>
      <reactants>CO(S):1.0 PT(S):1</reactants>
      <products>C(S):1.0 O(S):1</products>
    </reaction>
  </reactionData>
</ctml>
