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[Doc] Describe Peng-Robinson input parameters
Also link from phase thermo model to species thermo model for Peng-Robinson and Redlich-Kwong models.
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@@ -857,7 +857,7 @@ A multi-species Redlich-Kwong phase as
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`described here <https://cantera.org/documentation/dev/doxygen/html/d6/d29/classCantera_1_1RedlichKwongMFTP.html#details>`__.
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The parameters for each species are contained in the corresponding species
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entries.
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entries. See :ref:`Redlich-Kwong species equation of state <sec-yaml-eos-redlich-kwong>`.
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.. _sec-yaml-Peng-Robinson:
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@@ -868,7 +868,7 @@ A multi-species Peng-Robinson phase as
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`described here <https://cantera.org/documentation/dev/doxygen/html/d3/ddc/classCantera_1_1PengRobinson.html#details>`__.
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The parameters for each species are contained in the corresponding species
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entries.
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entries. See :ref:`Peng-Robinson species equation of state <sec-yaml-eos-peng-robinson>`.
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.. _sec-yaml-plasma:
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@@ -245,6 +245,21 @@ Example::
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data: {298.15: -91.50963, 333.15: -85.0}
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.. _sec-yaml-species-crit-props:
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Species critical state parameters
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=================================
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``critical-temperature``
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The critical temperature of the species [K]
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``critical-pressure``
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The critical pressure of the species [Pa]
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``acentric-factor``
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Pitzer's acentric factor :math:`omega` [-]
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.. _sec-yaml-species-eos:
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Species equation of state models
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@@ -261,21 +276,9 @@ Species equation of state models
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- :ref:`ions-from-neutral-molecule <sec-yaml-eos-ions-from-neutral>`
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- :ref:`liquid-water-IAPWS95 <sec-yaml-eos-liquid-water-iapws95>`
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- :ref:`molar-volume-temperature-polynomial <sec-yaml-eos-molar-volume-temperature-polynomial>`
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- :ref:`Peng-Robinson <sec-yaml-eos-peng-robinson>`
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- :ref:`Redlich-Kwong <sec-yaml-eos-redlich-kwong>`
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.. _sec-yaml-species-crit-props:
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Species critical state parameters
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=================================
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``critical-temperature``
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The critical temperature of the species.
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``critical-pressure``
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The critical pressure of the species.
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``acentric-factor``
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Pitzer's acentric factor :math:`omega`.
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.. _sec-yaml-eos-constant-volume:
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@@ -418,6 +421,41 @@ Additional fields:
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``data``
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Vector of 4 coefficients for a cubic polynomial in temperature
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.. _sec-yaml-eos-peng-robinson:
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Peng-Robinson
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-------------
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A model where species follow the Peng-Robinson equation of state as
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`described here <https://cantera.org/documentation/dev/doxygen/html/d3/ddc/classCantera_1_1PengRobinson.html#details>`__.
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Additional fields:
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``a``
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Pure-species ``a`` coefficient [Pa*m^6/kmol^2]
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``b``
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Pure-species ``b`` coefficient [m^3/kmol]
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``acentric-factor``
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Pitzer's acentric factor [-]
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``binary-a``
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Optional mapping where the keys are species names and the values are the ``a``
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coefficients for binary interactions between the two species.
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Example::
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equation-of-state:
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model: Peng-Robinson
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units: {length: cm, quantity: mol}
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a: 5.998873E+11
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b: 18.9714
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acentric-factor: 0.344
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binary-a:
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H2: 4 bar*cm^6/mol^2
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CO2: 7.897e7 bar*cm^6/mol^2
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.. _sec-yaml-eos-redlich-kwong:
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